She presented the show with Konnie Huq, Simon Thomas, Matt Baker, Liz Barker, Gethin Jones and Andy Akinwolere.
Shortly after her debut, she famously said "I'd Try Anything Once", which started a trend in her being asked to do dangerous or embarrassing things including wing-walking on top of an antique biplane and stamp collecting.
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Following John Bean's lead, one of the RF-603n's was to be put atop the Sonia digital slave unit (with programmable preflashes-ignored), .
In 2009 she was placed at number 20 on FHM's 100 sexiest women.
Salmon was revealed as the 30th Blue Peter presenter on 25 October 2004.
When she mentioned in her blog on the Blue Peter website that she had an ambition to be sawn in half by a magician, viewers started a campaign for her to do a challenge where she would become a magician's assistant.
This campaign was successful, and Salmon filmed a challenge where she assisted a magician with a number of illusions including levitation and a transposition illusion called "The Assistants Revenge".